Menu Links

News

Direct Detection of Supramolecular Reaction Centers in the Methanol-to-Olefins Conversion over Zeolite H-ZSM-5 by 13C–27Al Solid-State NMR Spectroscopy

Release time:2016-4-20      Source:admin      Reads:591

 

-------------------------------------------------------------------------------

 

     Pooled resources: The formation of supramolecular reaction centers composed of organic hydrocarbon-pool (HP) species and a zeolite framework is shown by 13C–27Aldouble-resonance solid-state NMR spectroscopy. The distance between 13C atoms (HP species) and 27Al atoms (zeolite) determines the reactivity of the HP species in the methanol-to-olefins conversion over H-ZSM-5 zeolite.

 

 

 

http://onlinelibrary.wiley.com/doi/10.1002/anie.201510920/full

 

-------------------------------------------------------------------------------

Back>>Top︿